Click this link to watch a few short videos on energy use in an existing home.
This book will provide you with some ideas of areas where energy can be wasted in an existing home.
Home Energy Use 101
Windows
A typical wall construction using 2 inch by 6 inch studs and insulated with fiberglass batts will have an R-value of 19. The best, most efficient, windows will have R-values closer to an R-6 or lower. As a result windows can be areas for greater heat loss than walls. This video will cover some of the energy basics of windows.